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Computing Radiative Parameters for the CsLi+ and LiK+ Molecular Ions

Authors: Smirnov A.D. Published: 27.09.2017
Published in issue: #5(74)/2017  
DOI: 10.18698/1812-3368-2017-5-67-77

 
Category: Physics | Chapter: Plasma Physics  
Keywords: Potential energy curve, radial wave equation, oscillator strength, radiative lifetime of the excited state, Franck — Condon factors, einstein coefficients

We computed radiative parameters (Einstein coefficient, absorption oscillator strength, Franck --- Condon factors, vibronic transition wavenumbers in (2)2Σ+−X2Σ+ band systems) for the CsLi+ (0 < v" < 15, 0 < v" < 51) and LiK+ (0 < v' < 15, 0< v" < 46) molecular ions, plus radiative lifetimes of excited electron states. We conducted our calculations based on potential energy curves plotted in our work. We solved the radial wave equation numerically in order to determine the vibrational energies and corresponding wavefunctions required for the computation. This is the first time that these radiative parameters and lifetimes were computed

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