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Calculation of Spectroscopic Constants for Electron States (2)1Σ+g , (1)1Πu(B), (1)1Πg, (2)1Πu(C) of Rubidium Dimmer

Authors: Smirnov A.D. Published: 17.10.2013
Published in issue: #4(39)/2010  
DOI:

 
Category: Physics  
Keywords: potential energy curves, radial wave equation, oscillatory, rotary, and centrifugal constants, Frank-Condon factors, Rv'v"-centroids

The calculation of oscillatory, rotary, and centrifugal constants is performed for electron states (2)1Εg+, (1)1Пu(В), (1)1Пg, (2)1Пu(С) and the calculation of Frank-Condon factors and Rvv»-centroids is conducted for electron transitions (1)1Пu(В)-(1)1Εg+(X), (2)1Пu(С)-(1)1Εg+(X), (2)1Пu(С)-(1)1Пg, (2)1Пu(С)-(2)1Εg+ of the molecule 85Rb2. The calculations are performed on the basis of the constructed semi-empirical potential curves. Results of calculation of spectroscopic constants are compared to experimental data.