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Capabilities of Photon Correlation Spectroscopy Method in the Study of Processes of Associate Formation

Authors: Pichugina A.A., Tsyro L.V., Aleksandrova S.Ya., Unger F.G. Published: 22.11.2017
Published in issue: #6(75)/2017  
DOI: 10.18698/1812-3368-2017-6-88-95

 
Category: Chemistry | Chapter: Bioorganic Chemistry  
Keywords: gallstone, free radicals, photon correlation spectroscopy, colloidal system

The study shows that gallstone dissolution in benzene forms a colloidal system based on exchange interactions, in which several competing processes may proceed: homolytic dissociation of diamagnetic molecules; recombination of radicals; formation of associates. The flow of such processes is due to the fact that benzene has a π-orbital, in which electrons are separated in space system, which may result in exchange interaction between the radical electron and any electron π-bond, i. e. the process of associate formation. If a gallstone--benzene solvent of a different nature --- hexane is added in the resulting system, the dispersed phase is rejected

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